Properties of Hydrocarbon Gases - Drilling Knowledge

Flaring Gas Testing

According to the US National Fire Protection Association, flammable (combustible) gases are those which burn in the concentrations of oxygen normally present in air. The burning of flammable gases is similar to that of flammable hydrocarbon liquid vapours, as a specific ignition temperature is needed to initiate the burning reaction and each will burn only within a certain defined range of gas-air mixtures. Flammable liquids have a flashpoint (the temperature (always below the boiling point) at which they emit sufficient vapours for combustion). There is no apparent flashpoint for flammable gases, as they are normally at temperatures above their boiling points, even when liquefied, and are therefore always at temperatures well in excess of their flashpoints.

The US National Fire Protection Association (1976) defines compressed and liquefied gases, as follows:

·     “Compressed gases are those which at all normal atmospheric temperatures inside their containers, exist solely in the gaseous state under pressure.”

·     “Liquefied gases are those which at normal atmospheric temperatures inside their containers, exist partly in the liquid state and partly in the gaseous state, and are under pressure as long as any liquid remains in the container.”

The major factor which determines the pressure inside the vessel is the temperature of the liquid stored. When exposed to the atmosphere, the liquefied gas very rapidly vaporizes, travelling along the ground or water surface unless dispersed into the air by wind or mechanical air movement. At normal atmospheric temperatures, about one-third of the liquid in the container will vaporize.

Flammable gases are further classified as fuel gas and industrial gas. Fuel gases, including natural gas and liquefied petroleum gases (propane and butane), are burned with air to produce heat in ovens, furnaces, water heaters and boilers. Flammable industrial gases, such as acetylene, are used in processing, welding, cutting and heat treating operations.